formaldehyde gas sds

Absorb with DRY earth or non-combustible material. Using OECD Guide-line 301D (Ready Biodegradability: Closed Bottle Test), formaldehyde achieved 90% in 28 days using non-acclimated inoculum which classified the compound as readily biodegradable(2). Very reactive, combines readily with many substances, 40% solution is powerful reducing agent. Contact causes white discoloration, smarting, cra cking and scaling. For UN3508, be aware of possible short circuiting as this product is transported in a charged state. Personal protection: gas-tight chemical protection suit including self-contained breathing apparatus. endobj Rinse with plenty of water (remove contact lenses if easily possible). Studies produced a weak association (limited evidence) between adverse human female reproductive effects and occupational exposure. Consult an expert! Flammable solid. Also, a positive association has been observed between exposure to formaldehyde and sinonasal cancer. : A registration number is not available for this substance as the substance or its uses are … Keep upwind to avoid inhalation of gases, vapours, fumes and smoke. (USCG, 1999). 77, No. Polymerization reaction with phenol may develop sudden destructive pressure [Bretherick, 5th ed., 1995, p.168]. Ensure airborne concentrations of formaldehyde do not exceed published exposure limits. An increased incidence of menstrual disorders were observed in female workers using urea-formaldehyde resins. There is sufficient evidence in humans for the carcinogenicity of formaldehyde. Materials containing formaldehyde can release it as a gas or vapor into the air. According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC). C - Corrosive. read more → Formaldehyde in PBS is a common fixitive reagent for histology in light microscopy and EM applications.... read more → 4-5 ppm, increased discomfort, mild lacrimation. 9999% Product use :Synthetic/Analytical chemistry. Particularly relevant to the discussions regarding sufficient evidence was a recent study accepted for publication which, for the first time, reported aneuploidy in blood of exposed workers characteristic of myeloid leukaemia and myelodysplastic syndromes, with supporting information suggesting a decrease in the major circulating blood-cell types and in circulating haematological precursor cells. Cool. May cause allergic respiratory and skin reaction. May generate toxic formaldehyde gas when heated. Evacuate personnel to safe areas. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. The PCBU must also obtain a copy of the safety data sheet and make it readil… Safety glasses with side-shields conforming to EN166. .sds-ghs .header, .sds-ghs .content { font-family: 'times_new_roman', 'Times New Roman', sans-serif; } .avoid-page-break-inside { page-break-inside:avoid; } .sds-ghs h1, .sds-ghs h2, .sds-ghs h3, .sds-ghs h4, .sds-ghs h5, .sds-ghs h6 { font-weight: bold; } .sds-ghs h1 { text-align: left; font-size: 2em; margin: 0.67em 0; } .sds-ghs h2 { text-align: left; color: grey; font-size: 1.2em; margin: 0.83em 0; } .sds-ghs h3 { font-size: 1.17em; margin: 10px 0; } .sds-ghs h4 { /*text-align:center;*/ font-size: 1em; margin: 10px 0; } .sds-ghs h5 { font-style: italic; color: grey; font-size: 0.83em; margin: 10px 0; } .sds-ghs p { /*border: 1px solid blue;*/ color: black; line-height: 1; margin-bottom: 5px; } .sds-ghs hr { /*border: 1px solid blue;*/ color: black; margin: 0.5em 0; } .sds-ghs table { width: 100%; border-collapse: collapse; } .sds-ghs table td, .sds-ghs table th { border: 1px solid black; text-align: center; line-height: 1.5em; } .sds-ghs .subtitle { font-size: 12px; color: grey; text-align: right; } .sds-ghs .table-border-none th, .sds-ghs .table-border-none td { border: none; text-align: left; vertical-align: top; line-height: 1; } .sds-ghs .width-pc-70 { width: 70%; } .sds-ghs .width-pc-30 { width: 30%; } .sds-ghs .width-100 { width: 100px; } .sds-ghs .title-number { width: 50px; float: left; display: inline-block; } .sds-ghs .title-content { padding-left: 50px; display: block; } .sds-ghs .title { margin-right: -50px; border-top: 1px solid; } .sds-ghs .content { margin-left: 50px; margin-right: 50px; } .sds-ghs .m-t { margin-top: 15px; } .sds-ghs .text-left { text-align: left; } .sds-ghs h3 { margin-left: -50px; } .sds-ghs h3:before { clear: both; content: ''; }, H314 Causes severe skin burns and eye damage, H341 Suspected of causing genetic defects. It also has minor uses in agriculture, as an analytical reagent, in concrete and plaster additives, cosmetics, disinfectants, fumigants, photography, and wood preservation. Formaldehyde –urea resin is used as an insulating material in building construction. 2 0 obj Nonflammable Gas Mixture: Formaldehyde 1ppb-999ppm / Nitrogen 99.9001-99.9999% Not available. Do NOT induce vomiting. Rinse skin with plenty of water or shower. Artificial respiration may be needed. Formaldehyde Formaldehyde (HCHO) CAS 50-00-0; UN 1198, UN 2209 (formalin) ... • Formaldehyde is a colorless, highly toxic, and flammable gas at room temperature that is slightly heavier than air. Will burn if involved in a fire and give off noxious fumes (e.g. The gas is a more dangerous fire hazard than the vapor.The gas mixes well with air, explosive mixtures are easily formed.Dust explosion possible if in powder or granular form, mixed with air. 1 0 obj Incompatible with liquid oxygen. Liq. Carc. Acute -- below 1 ppm, odor perceptible to most. Formaldehyde (Formalin) 50-00-0 200-001-8 5.00 % v/v T - Toxic. Fireproof. Do not discharge to sewer systems. Product identifier . P201 Obtain special instructions before use. Treat coma and shock if they occur. 5.2. Metals such as platinum, copper, chromia, and alumina also catalyze the formation of methanol, methylformate, formic acid, carbon dioxide, and methane. Acute exposure to formaldehyde can have a corrosive effect on the respiratory tract, gastrointestinal system, and skin. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Methanol 67-56-1 200-659-6 1.00 % v/v F - Highly flammable. Avoid dust formation. Wash and dry hands. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Formaldehyde Solution Flinn Scientific, Inc. P.O. 3. Some may be transported hot. Automobile exhaust is a major source of formaldehyde in outdoor air. R34- Causes burns. Rinse mouth. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. It is used as a denaturant in formaldehyde-agarose gel electrophoresis of RNA. The authors and Working Group felt that this study needed to be replicated. Flammable liquid when exposed to heat or flame; can react vigorously with oxidizers. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P403+P233 Store in a well-ventilated place. 1.3. a. Vapors may cause dizziness or suffocation. Flash Point: 70 deg C. Warning! Reacts with nitrogen oxides at about 180; the reaction becomes explosive. Can react with air to give first peroxo acids, and ultimately formic acid. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. Product name : Formaldehyde, 10% v/v, Buffered Product code : LC14670 . Formaldehyde gas adsorbs on clay minerals to a degree at high gas concentrations which is an important quality in its use as a soil fumigant(4). Evacuate danger area! P280 Wear protective gloves/protective clothing/eye protection/face protection. Formaldehyde is carcinogenic to humans (Group 1). Also reacts violently with perchloric acid-aniline, performic acid, nitromethane, magnesium carbonate, and hydrogen peroxide. Product Name : FORMALDEHYDE SOLUTION 37 w/w, stablized with 10-12% methanol Classified as hazardous 1. Use water spray, dry chemical, alcohol foam, or carbon dioxide. The main products are carbon monoxide and hydrogen. 1 (H317), Muta. There is sufficient evidence in experimental animals for the carcinogenicity of formaldehyde. Most vapors are heavier than air. Other biodegradation screening tests gave half-lives ranging from <1 to 17.3 days(7-12). (ERG, 2016), Behavior in Fire: Changes to formaldehyde gas, which is highly flammable. P308+P313 IF exposed or concerned: Get medical advice/ attention. purest form, formaldehyde is a colorless, highly toxic and flammable gas with the chemical formula HCHO or CH 2 O. Containers may explode when heated. Explosion hazard: when aqueous formaldehyde solutions are heated above their flash points, a potential for explosion hazard exists. Gas. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9804 Signal Word DANGER. Delayed -- sensitization dermatitis. Continue rinsing. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. stream (ERG, 2016), Toxic vapors such as carbon dioxide and carbon monoxide are generated during combustion. P270 Do not eat, drink or smoke when using this product. 3 (H301 + H311 + H331), Skin Corr. View product specific information, MSDS, References and Buying FAQ. <> Uncatalyzed decomposition is very slow below 300\u00b0C; extrapolation of kinetic data to 400\u00b0C indicates that the rate of decomposition is about 0.44%/min at 101 kPa (1 atm). Fresh air, rest. P302+P352 IF ON SKIN: Wash with plenty of water/... P312 Call a POISON CENTER/doctor/\u2026if you feel unwell. For personal protection see section 8. Formaldehyde: health effects, incident management and toxicology Information on formaldehyde (also known as methanal and methylene glycol) for use in responding to chemical incidents. 3 Xi - Irritant. /Formaldehyde/ /Formalin (as formaldehyde)/, NIOSH usually recommends that occupational exposures to carcinogens be limited to the lowest feasible concentration. Sodium carbonate, ammonium hydroxide, or sodium sulfite can neutralize the spill. But few homes are now insulated with UFFI. Formaldehyde (/ f ə r ˈ m æ l d ə h aɪ d / fer-mal-duh-hahyd, also / f ɔːr ˈ m æ l d ə h aɪ d / fawr-) (systematic name methanal) is a naturally occurring organic compound with the formula CH 2 O (H−CHO). California … Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Revision Date: April 15, 2016. /Formaldehyde/ /Formalin (as formaldehyde)/. E-mail (competent person) SDS@vwr.com 1.4 Emergency phone number Telephone +44 (0) 1270 502894 (CareChem24) 2 / 14 SECTION 2: Hazard identification 2.1 Classification of the substance or mixture 2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP] Hazard classes and hazard categories Hazard statements Acute toxicity, category 3, oral, dermal and inhalation … <>>> SAFETY DATA SHEET GHS product identifier Other means of identification Product type Section 1. State Regulations. A study of hospital equipment sterilizing workers did not report an association between formaldehyde exposure and increased spontaneous abortions. Remove contact lenses, if present and easy to do. Homes in which UFFI was installed many years ago are not likely to have high formaldehyde levels now. Treat bronchospasm and pulmonary edema if they occur. Formaldehyde exposure can also happen in offices and newly constructed homes via off-gas from wood products, paints and finishes, and cigarette smoke. 2 (H225); … General description Formaldehyde (formalin) is produced by oxidation of methanol. It can cause irreversible eye damage in instances of severe overexposure. Administer supplemental oxygen, and observe for at least 4 to 6 hours. For precautions see section 2.2. b. Administer intravenous saline or other crystalloids to replace fluid losses caused by gastroenteritis. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Advice for fire-fighters: Self-contained breathing apparatus and protective clothing. 1B (H350) Concentration: < 5% Component: Methanol CAS No: 67-56-1 EC No: 200-659-6 Index No: 603-001 -00-x Registration No: 01-2119433307 -44-xxxx Classification: Flam. … 10-20 ppm, breathing difficult, cough, severe burning of nose and throat. Many liquids are lighter than water. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. A person conducting a business or undertaking (PCBU) must correctly labelhazardous chemicals used, handled or stored at the workplace, including containers and pipework. Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 5.2 SDS Revision Date: 7/20/2018 5. Avoid breathing dust. Metals such as platinium, copper, chromia, and alumina also catalyze the formation of methanol, methylformate, formic acid, carbon dioxide, and methane. May be ignited by heat, sparks or flames. Vapor explosion hazard indoors, outdoors or in sewers. Runoff from fire control or dilution water may cause pollution. The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Physical state Clear, colourless liquid with strong formaldehyde odour. Show this safety data sheet to the doctor in attendance. Wear self-contained breathing apparatus for firefighting if necessary. 1.2. Use of the substance/mixture : For laboratory and manufacturing us e only. Will polymerize violently in the presence of caustics and nitrides; (amines) exothermic reaction, (Azo compound) exothermic reaction giving off nitrogen gas, (caustics) heat generation and violent polymerization, (dithiocarbamates) formation of flammable gases and toxic fumes, formation of carbon disulfide may result, (alkali and alkaline earth metals) heat generation and formation of a flammable hydrogen gas. SDS complies with OSHA’s Hazard Communication Rule 29, CFR 1910.1200. Skin -- primary irritation from strong solutions, gas. May react with bases (sodium hydroxide, potassium hydroxide, ammonia), and with nitrogen dioxide (explosive reaction around 180\u00b0C). /Formaldehyde/ /Formalin (as formaldehyde)/, Recommended Exposure Limit: 15 Minute Ceiling Value: 0.1 ppm. Supplier . Vapors may travel to source of ignition and flash back. High formaldehyde concentration or methanol content lowers flash point. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. Consult a physician. SARA: Section 355 (extremely hazardous substances): 50-00-0 formaldehyde. SECTION 2 — HAZARDS IDENTIFICATION. Wash hands before breaks and at the end of workday. When heated, irritant formaldehyde gas evolved from solution. Odour Threshold: 0,05 – 0,125 ppm (Formaldehyde) pH: 2,8 – 4,0 at 20°C Melting point: < -15°C Boiling point/boiling range: 93-96°C at 1.013 hPa Flash point: 62°C Method: c.c Evaporation rate: No information available Flammability (solid, gas): No information available Causes eye, skin, and respiratory tract irritation. Do NOT induce vomiting. Runoff to sewer may create fire or explosion hazard. In people sensitized to formaldehyde, late asthmatic reactions may be provoked by brief exposures at approximately 3 ppm. May generate flammable and/or toxic gases in combination with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. Hazard class: Flammable liquids (Category 3). Formaldehyde is a severe skin irritant and sensitizer. Experiments performed on a variety of fish and shrimp showed no bioconcentration of formaldehyde(4,5). Formaldehyde may also be used under restriction in the EUas a preservative in cosmetics and nail hardening products. Use D-Formalizer® pads or F.C.G.® Formaldehyde Control Granules to reduce formaldehyde exposure. Formaldehyde (as urea formaldehyde foam) was extensively used as an insulating material until 1982 when it was banned by the U.S. Consumer Product Safety Commission. However, possible confounding factors were not evaluated in this study. Hazardous polymerization may occur. P271 Use only outdoors or in a well-ventilated area. Vapour is heavier than air and is an explosion hazard. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. may react violently with strong oxidizing agents (hydrogen peroxide, performic acid, perchloric acid in the presence of aniline, potassium permanganate, nitromethane). An estimated BCF of 3 was calculated for formaldehyde(SRC), using a log Kow of 0.35(1) and a regression-derived equation(2). Service Tel: +86-571-87759741, Marketing Tel: +86-571-89739798 skype, Copyright©2010-2021 Guidechem 浙B2-20090288-37, Recommended use of the chemical and restrictions on use, Classification of the substance or mixture, GHS label elements, including precautionary statements, Other hazards which do not result in classification, Description of necessary first-aid measures, Most important symptoms/effects, acute and delayed, Indication of immediate medical attention and special treatment needed, if necessary, Specific hazards arising from the chemical, Special protective actions for fire-fighters, Personal precautions, protective equipment and emergency procedures, Methods and materials for containment and cleaning up, Conditions for safe storage, including any incompatibilities, Individual protection measures, such as personal protective equipment (PPE), Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code, Safety, health and environmental regulations specific for the product in question, 3-Methoxy-4-(1-pyrrolidinyl)benzenediazonium trichlorozincate, polymer with formaldehyde, formaldehyde,(4-hydroxyphenyl)arsonic acid, Melamine, formaldehyde, toluenesulfonamide polymer, butylated, Benzoic acid, 2-hydroxy-, polymer with 4-(1,1-dimethylethyl)phenol and formaldehyde, sodium salt, formaldehyde; 2-methyloxirane; 4-nonylphenol; oxirane, 2,2'-Methylenebis(5,5-dimethylcyclohexane-1,3-dione), Methanethioic acid, S-1H-benzimidazol-2-yl ester (9CI), High quality Formaldehyde Cas 50-00-0 with favorable price, High Quality Formaldehyde chinese supplier, Best price Formaldehyde/Formalin/CAS:50-00-0. Handle with gloves. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. DOWNLOAD MSDS (PDF) | Search MSDS currently available for download bioWORLD offers Formaldehyde (4%) in PBS for your research at low price. Prevent firefighting water entering watercourses or ground-water. R43- May cause sensitization by skin contact. Formaldehyde resins are used as adhesives and binders in many different industries that produce wood products, pulp and paper, synthetic fibres, plastics and coating and textiles. In a die-away test using water from a stagnant lake, degradation was complete in 30 hours under aerobic conditions(6). The Koc of formaldehyde is estimated as 8(SRC), using a log Kow of 0.35(1) and a regression-derived equation(2). Refer immediately for medical attention. One of the most common uses of formaldehyde in the U.S is manufacturing urea-formaldehyde resins, used in particleboard products. These reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). : 605-001-00-5 REACH No. Remove gas with fine water spray. When heated, irritant formaldehyde gas evolved from solution. Formaldehyde: off-gas : 200-001-8: Section 3 - Hazards Identification EMERGENCY OVERVIEW. Minimum storage temperature to prevent polymerization range from 83 deg F for 37% formaldehyde containing 0.05% methyl alcohol to 29 deg F for formaldehyde containing 15% methyl alcohol. In laboratories, the gas is more commonly dissolved in water and used as an aqueous solution called formalin. endobj They can be exposed during the treatment of tex- tiles and the production of resins. Inhalation. 2 (H341), Carc. pH 2.8 – 4.0 (25 degrees Celsius) (37% solution) Odour threshold 0.8 – 1ppm Percent volatile … Keep container tightly closed. Safety Data Sheet Sodium Formaldehyde Bisulphite Solution SDS 26/7 Page n. 3 of 8 None in particular. P363 Wash contaminated clothing before reuse. Use water to keep fire exposed containers cool. Remove contaminated clothes. 1B (H314), Skin Sens. 50-100 ppm, acute irritation of respiratory tract, very serious injury likely. Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Some may burn but none ignite readily. Avoid breathing vapours, mist or gas. AEROBIC: Formaldehyde, present at 100 mg/L, reached 91% of its theoretical BOD in 2 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test which classified the compound as readily biodegradable(1). P301+P330+P331 IF SWALLOWED: Rinse mouth. Wear impervious clothing. R40- Limited evidence of a carcinogenic effect. Suspected carcinogen. Higher concentrations or splashes may cause irreversible eye damage. Avoid fluid overload in patients with inhalation exposure because of the risk of pulmonary edema. FORMALDEHYDE 37-40% W/V LRG Protective actions during firefighting Avoid breathing fire gases or vapours. Seek medical attention if you feel unwell. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Commercial formaldehyde-alcohol solutions are stable. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Avoid oxidizing and alkaline materials. The main products of decomposition are carbon monoxide and hydrogen. Compound will polymerize with active organic materials such as phenol. Formaldehyde causes cancer of the nasopharynx and leukaemia. /Pure formaldehyde/, Lower flammable limit: 7.0% by volume; Upper flammable limit: 73% by volume, In water:soluble, > 100\u2009g/100 ml\uff0820\u2009\u00b0C\uff09, ADR/RID: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, IMDG: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, IATA: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, Oral: LD50 Rat oral 100 mg/kg /SRP: percent solution not specified/, Inhalation: LC50 Rat inhalation 0.82 mg/L (1/2 hour), Dermal: LD50 Rabbit percutaneous 270 mg/kg /Formalin/, Toxicity to fish: LC50; Species: Oncorhynchus mykiss (Rainbow trout) weight 0.63 g; Conditions: static; Concentration: 118 ppm for 96 hr (95% confidence limit: 99.7-140 ppm) /37% AI formulated product, Toxicity to daphnia and other aquatic invertebrates: EC50; Species: Daphnia magna (Water Flea) age <24 hr; Conditions: freshwater, static; Concentration: 14600 ug/L for 48 hr (95% confidence interval: 11300-18000 ug/L); Effect: intoxication, immobilization /37% purity, Toxicity to algae: EC50; Species: Scenedesmus subspicatus (Green Algae); Conditions: freshwater, static; Concentration: 211000 ug/L for 49-79 min; Effect: population, decreased photosynthesis /formulation, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. Can react with hydrogen chloride or other inorganic chlorides to form bis-chloromethylether (BCME), a known carcinogen. Product may generate formaldehyde which can … %PDF-1.5 (EPA, 1998), Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: Flammable/combustible material. Gas is stable in absence of water. Formaldehyde is produced in large quantities industrially. Advice for firefighters Use suitable breathing apparatus. On standing, especially in the cold, may become cloudy, and on exposure to very low temperature ppt of trioxymethylene formed; in air it slowly oxidizes to formic acid /40% solution/. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 11/15/2013 Revision date: 02/27/2014 Supersedes: 11/15/2013 Version: 1.1 03/05/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking . (EPA, 1998), Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: May cause toxic effects if inhaled or ingested/swallowed. Formalin solutions typically use up to 15% methanol as a stabilizer. %µµµµ Reacts with peroxide, nitrogen oxide, and performic acid causing explosions. R11- Highly flammable. endobj Rinse skin with water [or shower]. If dry, it can be charged electrostatically by swirling, pneumatic transport, pouring, etc.FORMALDEHYDE (ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.) Large Spill and Leak: Stop leak if it is safe to do so. Ventilate closed spaces before entering them. Turn off gas at source if possible. xœÍ[ÝsÓH§Šÿaí=2Ö|¨­­3¶ÙMH66µÅÁ>øŒ ¾Kbλpýu÷H¶dideñőåžéÏéùuÏ0n²ÕÇù"c?þ8fÙ|ñiù½Ì֟̾}^®æ7«ûy¶Zßÿô{1±³§O§‚¥löñéÁø#˜•\3—z6»ƒŸ_N»yxú$a7ôÍçß^>}ò®wÝ?Q½eßôþX=ômoÕW½uÿÄôîáϳ%¼|ÞÿÍ~~úd̐aÁFÍ­Ü2z×cQBË­-^Ì7Àh¼? Handle in accordance with good industrial hygiene and safety practice. SARA Title III: Section 313 (Specific toxic chemical listings): 50-00-0 formaldehyde, 67-56-1 Methyl Alcohol RCRA: ND TSCA: All ingredients are listed. T - Toxic. CERCLA: Formaldehyde 50-00-0: RQ = 100 lbs (45.4 Kg). Formaldehyde is used predominantly as a chemical intermediate. Cat. Recommended use and restrictions on use . Reacts with nitrogen oxides at about 180; the reaction becomes explosive. May react with hydrochloric acid to form highly toxic bis(chloromethyl) ether. Suppliers of a hazardous chemical to a workplace must provide current safety data sheets. According to a classification scheme(3), this estimated Koc value suggests that formaldehyde is expected to have very high mobility in soil(SRC). Manufacturers and importers of formaldehyde/formalin need to ensure that hazardous chemicals are labelled and that safety data sheets are prepared and provided. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. 3 0 obj Avoid formation of dust and aerosols. Ingestion. Evacuate area. Gloves must be inspected prior to use. Ensure adequate ventilation. P362+P364 Take off contaminated clothing and wash it before reuse. Use fluorocarbon water spray, Cellosize and Hycar to diminish vapors. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Very few human studies have been done on the adverse reproductive effects from exposure to Formaldehyde. Appearance: white powder. SDS #: 352. SDS # :012612 Airgas USA, LLC … May be harmful if swallowed or absorbed through the skin. Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). 10 ppm, profuse lacrimation; can be withstood only for few minutes. Workers can inhale formaldehyde as a gas or vapour or absorb it through the skin as a liquid. Containers may explode when heated. GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name Formaldehyde solution, 36.5: -38% Product Number : F8775 Brand : Sigma Index-No. It is mainly used to produce other chemicals and in the production of resins. Solutions splashed in eyes have caused injuries ranging from severe, permanent corneal opacification and loss of vision to minor discomfort. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. In addition, formaldehyde may interact with humic substances in soil(5) resulting in decreased mobility. For… If leak or spill has not ignited, use water spray to disperse vapors, and to protect men attempting to stop leak. It is made of 37% formaldehyde and impurities such as methanol, small amounts of formic acid, aldehydes and ketones. Synonym :Monoxide; Flue gas; Carbon oxide; carbonic oxide; Monoxide of carbon; Carbon monooxide SDS # :001014 Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone :1-866-734-3438 Section 2.

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